Dissolved titanium distributions in the Mid-Atlantic Bight   总被引：1，自引：0，他引：1  

Stephen A. Skrabal   《Marine Chemistry》2006,102(3-4):218-229

Although titanium is abundant in Earth's crust, its sources and distribution in the ocean are poorly understood. To elucidate its behavior, distributions of dissolved (< 0.2 μm) Ti were determined in surface waters and vertical profiles from the Mid-Atlantic Bight (MAB). Concentrations of Ti decreased from 390 pM at the Delaware Bay mouth to < 100 pM across the Delaware continental shelf. In vertical profiles, small increases in bottom waters suggest a possible flux of Ti from shelf sediments, consistent with previous reports of pore water enrichments of dissolved Ti in MAB sediments. Concentrations in surface waters of the outer shelf and slope ranged between 30 and 140 pM, with most values below 90 pM. Concentrations in a 1000 m vertical profile in the eastern Gulf Stream ranged between 110 and 280 pM, and showed a variable distribution attributed to the mixing of water masses in the outer MAB. A simple model of Ti sources to the MAB suggests that atmospheric deposition of dissolved Ti is comparable to net riverine contributions and therefore must be considered in applications of Ti as a tracer of oceanographic processes.  相似文献   

Heavy metals in marine sediments of Taranto Gulf (Ionian Sea, Southern Italy)   总被引：5，自引：0，他引：5  

Alessandro Buccolieri  Giovanni Buccolieri  Nicola Cardellicchio  Angelo Dell'Atti  Antonella Di Leo  Antonella Maci 《Marine Chemistry》2006,99(1-4):227

Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments.  相似文献   

台湾海峡表层沉积物中重矿物特征及其物质来源   总被引：15，自引：0，他引：15  

陈华胃 《台湾海峡》1993,12(2):136-144

台湾海峡重矿物平均分布0.95%,其分布由西岸向东岸递减;由北部经台湾浅滩朝粤东方向缓慢递减。碎屑矿物46种,以角闪石、绿帘石、磁铁矿、钛铁矿、褐铁矿和片状矿物为主,它们占重矿物含量的67%。据主要重矿物含量将海峡分成8个矿物组合区。碎屑矿物来自海峡两岸基岩,通过河流搬运入海,有部分片状矿物为海峡以北的物质随浙闽沿岸流进入海峡而沉积。其海绿石是台湾西岸、澎湖岛第三系或第四系含海绿石岩层剥蚀后搬运入海沉积而成的。台湾浅滩的残留沉积物为晚更新世低海面时期的河口滨海相沉积物。由于处在开放的海洋环境,至今没有接受现代沉积。残留沉积物中的磁铁矿、钛铁矿、锆石等重矿物相对富集,含量高于近源海域,有可能赋存浅海砂矿。  相似文献   

Comparison of high spatial resolution trace metal distributions with model simulations for surface waters of the Gulf of Cadiz     

J.M. Beckers  E.P. Achterberg  Ch. Braungardt 《Estuarine, Coastal and Shelf Science》2007,74(4):599

A multidisciplinary study in the Gulf of Cadiz is revisited, using additional diagnostic modelling tools. The dissolved trace metal (Cu, Ni, Zn, Co) distributions in the Gulf of Cadiz are analysed using modelled tracer evolutions, field observations and the concept of tracer ages. This study shows that a significant part of the observed metal distributions can be explained by the metal inputs of three river systems (Guadiana, Rio Tinto and Odiel, Guadalquivir) discharging into the Gulf of Cadiz, while the remainder of the signal is most likely associated with the benthic metal remobilisation along the shelf of this coastal region.  相似文献   

翅碱蓬(Suaeda heteroptera)根际与非根际沉积物常见重金属总量及化学形态变化     

朱鸣鹤  丁永生  丁德文 《海洋与湖沼》2006,37(5):393-400

原子吸收光谱法和等离子光谱法分别研究了潮滩盐沼植物翅碱蓬(Suaedaheterop-tera)根际与非根际(根上部和根下部)沉积物中Cu、Zn、Pb和Cd的总量和化学形态。结果表明,从总量来看,不同潮滩沉积物中4种重金属次序均为Zn>Pb>Cu>Cd,但同一元素随潮滩位置变化明显,尤以中潮滩差异最显著,重金属总量明显大于其他两个潮滩(低潮滩和高潮滩),特别是根际沉积物中的重金属总量远高于非根际沉积物总量,其比值分别为Cu3·4—4·2倍,Zn2·2—2·7倍,Pb3·2—3·3倍。同一潮滩均表现为根际沉积物>根上部>根下部。Cd含量相对较低,其变化不明显。从化学形态看,沉积物重金属表现为环境直接影响态(交换态和有机结合态)、环境间接影响态(碳酸盐态和铁锰氧化物态)和稳定态(残渣态)。与非根际沉积物相比,根际沉积物中重金属的化学形态发生了显著的变化,Cu和Pb以稳定态为主,其次为环境间接影响态,环境直接影响态最低;Zn与上述2种金属不同,以环境直接影响态含量最高(可交换态是有机结合态的7倍),其次分别为环境间接影响态(主要是碳酸盐结合态)和稳定态。实验结果表明,由于特异根圈效应,一方面该植物使可迁移形态的Cu和Pb在根际逐步得到矿化,使其生物可利用性降低;另一方面使Zn的生物可利用性提高,促进了植物对Zn的吸收利用。  相似文献   

Size distribution of colloidal trace metals and organic carbon during a coastal bloom in the Baltic Sea   总被引：1，自引：0，他引：1  

Johan Ingri  Susanna Nordling  Jenny Larsson  Jenny Rnnegrd  Nina Nilsson  Ilia Rodushkin  Ralf Dahlqvist  Per Andersson   rjan Gustafsson 《Marine Chemistry》2004,91(1-4):117-130

The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown.  相似文献   

Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia   总被引：1，自引：0，他引：1  

Christophe Migon  Sylvain Ouillon  Xavier Mari  Emmanuel Nicolas 《Estuarine, Coastal and Shelf Science》2007,74(4):756

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.  相似文献   

ICES baseline survey of trace metals in European shelf waters   总被引：1，自引：0，他引：1  

Balls  P.; Cofino  W.; Schmidt  D.; Topping  G.; Wilson  S.; Yeats  P. 《ICES Journal of Marine Science》1993,50(4):435-444

  相似文献   

环境因子对贝类累积溶解态重金属的影响   总被引：10，自引：0，他引：10  

王静凤  张学成  单宝田 《中国海洋大学学报(自然科学版)》2005,35(3):382-386

对溶解态重金属的吸收是贝类累积重金属的重要来源之一，易受到生物因素和非生物因素的影响。综述溶解氧、温度、空气预暴露、化学物质预暴露等环境因子，诱导的机体代谢过程的改变，对溶解态重金属的累积和转运过程的影响。强调了贝类对溶解态重金属的转运除了被动转运之外，还涉及到需要ATP供能的主动转运过程。  相似文献   

离子色谱分析在黄土和粉尘研究中的应用   总被引：1，自引：0，他引：1  

王丹  屈文军  张小曳  严立文  曹国良 《海洋地质与第四纪地质》2005,25(1):113-118

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。  相似文献